Planar Graphene-Based Microsupercapacitors

With the development of wearable, portable, and implantable electronic devices, flexible and on-chip microsupercapacitors (MSCs) are urgently needed for miniaturized energy storage. Planar MSCs have high power density, fast charge/discharge rate, and long operating lifetime, and can adapt to future flexible, integrated, and miniaturized electronic systems for wide application foreground. Due to the high specific surface area, outstanding electrical conductivity, and excellent electron mobility, graphene shows promising advantages in planar MSCs devices, thus stimulates wide-ranging research in the last few years. Herein, the recent progress of planar graphene-based MSCs, including the intrinsic structure regulation of graphene-based electrode materials, the specific fabrication techniques, the multifunctional integration, and various applications of MSCs as flexible and on-chip energy storage is systematically summarized. The key challenges and prospects of future planar graphene-based MSCs are also discussed targeting to realize their practical applications.