Optimized CeO2 Nanowires with Rich Surface Oxygen Vacancies Enable Fast Li-Ion Conduction in Composite Polymer Electrolytes

Low-cost and flexible solid polymer electrolytes are promising in all-solid-state Li-metal batteries with high energy density and safety. However, both the low room-temperature ionic conductivities and the small Li+ transference number of these electrolytes significantly increase the internal resistance and overpotential of the battery. Here, we introduce Gd-doped CeO2 nanowires with large surface area and rich surface oxygen vacancies to the polymer electrolyte to increase the interaction between Gd-doped CeO2 nanowires and polymer electrolytes, which promotes the Li-salt dissociation and increases the concentration of mobile Li ions in the composite polymer electrolytes. The optimized composite polymer electrolyte has a high Li-ion conductivity of 5 x 10(-4) S cm(-1) at 30 degrees C and a large Li+ transference number of 0.47. Moreover, the composite polymer electrolytes have excellent compatibility with the metallic lithium anode and high-voltage LiNi0.8Mn0.1Co0.1O2 (NMC) cathode, providing the stable cycling of all-solid-state batteries at high current densities.