基本信息
浏览量:2
职业迁徙
个人简介
Cummins group research embraces chemical synthesis, reaction discovery, reagent development, and mechanistic studies. Under development are anthracene-based precursors to reactive intermediates including P2, aminophosphinidenes, SO, phosphinidene chalcogenides, and other heavier main-group multiply bonded species not stabilized by sterically demanding substituents. Group transfer reactivity is advancing in a parallel fashion. Ligands are being elaborated from P2 cycloaddition chemistry for catalysis applications. A building block approach to poly and oligophosphate containing compounds is gaining traction with reagents for tri and tetraphosphorylation of assorted nucleophiles. Transition-metal mediated processes for phosphinidene transfer to olefins are under elucidation towards development of a phosphiranation method, the phosphorus counterpart to epoxidation or aziridination. Synthetic sorties are complemented by quantum chemical investigations to illuminate potential energy surfaces and to reveal nuances of chemical bonding for novel systems. Phosphorus sustainability efforts are geared to uncovering energy efficient and waste minimal routes to value added P-chemicals starting from recovered and recycled materials.
研究兴趣
论文共 433 篇作者统计合作学者相似作者
按年份排序按引用量排序主题筛选期刊级别筛选合作者筛选合作机构筛选
时间
引用量
主题
期刊级别
合作者
合作机构
ACS central scienceno. 8 (2023): 1575-1580
引用1浏览0WOS引用
1
0
Inorganic chemistryno. 27 (2023): 10559-10571
Journal of the American Chemical Societyno. 48 (2023): 25989-25994
Journal of the American Chemical Societyno. 11 (2023): 6045-6050
加载更多
作者统计
合作学者
合作机构
D-Core
- 合作者
- 学生
- 导师
数据免责声明
页面数据均来自互联网公开来源、合作出版商和通过AI技术自动分析结果,我们不对页面数据的有效性、准确性、正确性、可靠性、完整性和及时性做出任何承诺和保证。若有疑问,可以通过电子邮件方式联系我们:report@aminer.cn