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An electrospray ionization source for thermochemical investigation with the guided ion beam mass spectrometer

Journal of The American Society for Mass Spectrometry, no. 6 (2007): 1124-1134

Cited: 83|Views22

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Laboratory Frame Electrospray Ionization Mass Spectrometry Kinetic Energy Distribution Protonated Water Cluster Thermochemical Investigation

Abstract

An electrospray ionization (ESI) source developed for use with the guided ion beam tandem mass spectrometer (GIBMS) is described. For accurate determination of thermochemistry using threshold collision-induced dissociation (TCID), it is essential that any source produces ions with four exacting characteristics: (1) high intensity, (2) s...More

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R. M. Moision

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P. B. Armentrout

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