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Ionic liquids made with dimethyl carbonate: solvents as well as boosted basic catalysts for the michael reaction.

CHEMISTRY-A EUROPEAN JOURNAL, no. 45 (2009): 12273-12282

Cited: 82|Views24
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Abstract

This article describes 1) a methodology for the green synthesis of a class of methylammonium and methylphosphonium ionic liquids (ILs), 2) how to tune their acid-base properties by anion exchange, 3) complete neat-phase NMR spectroscopic characterisation of these materials and 4) their application as active organocatalysts for base-promot...More

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