Mechanistic Observations on the Unusual Reactivity of Dioxenone Photosubstrates in the Synthesis of Ingenol

Jeffrey D. Winkler,Sean J. Harrison,Michael F. Greaney,Meagan B. Rouse

SYNTHESIS-STUTTGART（2002）

引用 5|浏览19

暂无评分

摘要

The irradiation of allylically substituted dioxenone photosubstrates 6 and 21 lead to unexpected products, the formation of which can be explained by a series of transannular hydrogen atom abstractions.

查看译文

关键词

photochemistry,natural products,rearrangements,radicals,cycloadditions

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要

Mechanistic Observations on the Unusual Reactivity of Dioxenone Photosubstrates­ in the Synthesis of Ingenol

Mechanistic Observations on the Unusual Reactivity of Dioxenone Photosubstrates in the Synthesis of Ingenol