Electrochemical-Behavior And Reactivity Of The Ag(Ii)/Ag(I)-Bipyridine System In Propylene Carbonate .2. Study Of The Agii(Bipy)2+/Agi(Bipy)+ Pair
ELECTROCHIMICA ACTA(1984)
摘要
Due to the reactivity expected in the presence of an excess Ag + with respect to the 1–2 stoichiometry (Ag-bipy), the electrochemical behaviour of the Ag(II)/Ag(I)-bipyridine system has been investigated using voltammetry and coulometry. The change in the current-potential curves has been rationalized taking into account an equilibrium between different species of Ag(I) in neutral or acidic media. Changes of the solution nature (ratio C bipy / C Ag ) or pH actually led to the formation of reactive species.
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