Characterisation and kinetic behaviour of H2Rh(PPh3)2(μ-Cl)2Rh(PPh3)(alkene) and related binuclear complexes detected during hydrogenation studies involving parahydrogen induced polarisation
CHEMICAL COMMUNICATIONS(2000)
摘要
When parahydrogen induced polarisation is used to examine hydrogenation reactions involving [Rh(mu-Cl)(PPh3)(2)](2) and RhCl(CO)(PMe3)(2), binuclear dihydride complexes are detected, characterised, and shown to be capable of alkene hydrogenation.
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kinetics
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