The electropolymerization of polycyclic hydrocarbons: substituent effects and reactivity/structure correlations
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry(1985)
摘要
The electrochemical oxidations of pyrene, fluorene and their derivatives yield conducting polymers with electrical conductivities of 10−1 to 1 S/cm. Their elemental analysis data indicate oxidation levels of 0.06 to 0.31 per monomer unit. Substituents determine whether electropolymerization occurs, or soluble products are formed instead. The relative importance of these pathways is dependent on the stability of the intermediate radical cation, and these are discussed in light of INDO molecular orbital calculations.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要