Predictions of which diastereoisomeric salt precipitates during an optical resolution via diastereoisomeric salt formation
TETRAHEDRON(1994)
摘要
The DSC data of sixteen conglomerate forming diastereoisomeric salt pairs were analysed. It was demonstrated that during optical resolution via fractional crystallization of diastereoisomeric salt pain always that diastereoisomeric salt precipitates which has the higher melting point. When one of the salts is amorphous that remains in the mother liquor. If one of the diastereoisomeric salt crystallizes with solvate that will precipitate during optical resolutions.
更多查看译文
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络