Preparation and diels-alder reactions of a pyranoid vinyl glycal:model studies for anthraquinone aglycone and carbohydrate syntheses

Bruce H. Lipshutz,Sam L. Nguyen,Todd R. Elworthy

TETRAHEDRON（1988）

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摘要

The preparation of a conjugated pyranoid vinyl glycal is reported, along with several of its thermal [4+2] cycloaddition reactions with a variety of dienophiles. Applications to the anthraquinone antitumor agents are discussed.

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