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Biochemical Evidence For An Editing Role Of Thioesterase Ii In The Biosynthesis Of The Polyketide Pikromycin

JOURNAL OF BIOLOGICAL CHEMISTRY, no. 50 (2002): 48028-48034

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The pikromycin biosynthetic gene cluster contains the pikAV gene encoding a type II thioesterase (TEII). TEII is not responsible for polyketide termination and cyclization, and its biosynthetic role has been unclear. During polyketide biosynthesis, extender units such as methylmalonyl acyl carrier protein (ACP) may prematurely decarboxyla...更多

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