Stereochemistry Of A Michaelis-Arbusov Reaction - Alkylation Of Optically Active Ethyl Trimethylsilyl Phenylphosphonite With Retention Of Configuration

G. R. van den Berg,D. H. J. M. Platenburg,H. P. Benschop

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS（1971）

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摘要

Ethylation of ethyl phenylphosphinate (I)via ethyl trimethylsilyl phenylphosphonite or via the corresponding trimethylstannyl ester, and free-radical addition of (I) to ethylene proceed with complete, or almost complete, retention of configuration.

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optical activity

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