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Projected Free Energies For Polydisperse Phase Equilibria

PHYSICAL REVIEW LETTERS, no. 7 (1998): 1365-1368

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A "polydisperse" system has an infinite number of conserved densities. We give a rational procedure for projecting its infinite-dimensional free energy surface onto a subspace comprising a finite number of linear combinations of densities ("moments"), in which the phase behavior is then found as usual. If the excess free energy of the sys...更多

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