Gold clusters. Reactivity of [Au9(PPh3)8]3+ and [Au8(PPh3)7]2+ towards isopropyl isocyanide

W. Bos,J.J. Bour,J.W.A. Van der Velden,J.J. Steggerda,A.L. Casalnuovo,L.H. Pignolet

Journal of Organometallic Chemistry（1983）

引用 19|浏览5

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摘要

Isopropyl isocyanide reacts with [Au9(PPh3)8]3+ or [Au8(PPh3)7]2+ in CH2Cl2 to give the cluster complex [Au9(PPh3)6(i-PrNC)2]X3 (X = NO3 or PF6), in which the peripheral Au atoms are bonded to PPh3 or i-PrNC. The complex has been characterized by elemental analysis, molecular weight, NMR, IR and Mössbauer spectroscopy.

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