Antiferromagnetic Interactions In A Distorted Cubane-Type Tetranuclear Manganese Cluster
INTERNATIONAL CONFERENCE ON MAGNETISM (ICM 2009)(2010)
摘要
We have synthesized a new tetranuclear manganese cluster with a distorted cubane-like [Mn4O4]-core. High field magnetization experiments reveal an intramolecular antiferromagnetic coupling between the four manganese ions. We explain our results both qualitatively and quantitatively by a simple spin square model in terms of four equal antiferromagnetic exchange interactions in the core with coupling strengths of J = -1.69 K.
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关键词
exchange interaction
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