Investigation of the processes of electrochemical perfluoroalkylation and fluorosulphation: Part 1. Electrode processes and the electrochemical perfluoroalkylation mechanism

The characteristics of the adsorption and electro-oxidation of perfluorocarboxylic acids and organic compounds, which are radical acceptors, on a plati of potential (0-3 V). The binding of radicals produced during the electrolysis of perfluorocarboxylates by perfluoro-olefins was studied using the elec that, depending on the radical structure and the nature of the solvent, perfluoroalkyl radicals participate in the reactions involved in the perfluoroa surface or dissolved in the solution bulk.