Synthesis, structure and electrochemical properties of the cationic complex tris-(imidazolidine-1,10-phenanthroline)iron(II)

Camilo García,Diego Villagra,Francesco Caruso,Miriam Rossi,Betty Matsuhiro,Leonora Mendoza,María J. Aguirre,Mauricio Isaacs

Inorganic Chemistry Communications（2009）

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摘要

The complex [FeII(Imz-phen)3](PF6)2, (Imz-phen=imidazolidine-[4,5-f]-1,10-phenanthroline), has been prepared and characterized using X-ray diffraction and spectroscopic techniques. A film is generated by cyclic voltammetry. The film shows electrocatalytic properties in the reduction of S(IV) oxoanions in ethanol/water solution.

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关键词

Iron phenanthrolines,Modified electrodes,Sulfite,Electrocatalysis,Polypyridyl ligands

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