Ruthenium-Catalysed Cleavage of Alkenes and Alkynes to Carboxylic Acids

William P Griffith,Abdel G Shoair,Maria Suriaatmaja

SYNTHETIC COMMUNICATIONS（2007）

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摘要

Catalysis of alkene and alkyne cleavage to carboxylic acids by ruthenium trichloride in the presence of an excess of periodic acid has been studied in biphasic H2O - CC4-CH3CN media, and is found to be simple and effective. The active catalyst is shown to be RuO4.

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