Formation of 1,2,3,6-Dioxadigermine in the Electron-Transfer Oxygenation of 1,2-Digermetene.

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS(1992)

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摘要
Photosensitized and cation radical-catalysed electron-transfer oxygenations of 3-phenyl-1,1,2,2-tetramesityl-1,2-digermetene 1 affords the corresponding 1,2,3,6-dioxadigermine 2 as a dioxygen insertion product into a Ge-Ge sigma-bond in moderate yields together with 1,2,5-oxadigermolene 3.
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electron transfer
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