Asymmetric synthesis of a chiral arsinophosphine via a metal template promoted asymmetric Diels–Alder reaction between diphenylvinylphosphine and 2-furyldiphenylarsine

Kien-Wee Tan,Fengli Liu,Yongxin Li,Geok-Kheng Tan,Pak-Hing Leung

Journal of Organometallic Chemistry（2006）

引用 15|浏览6

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摘要

The metal-template promoted asymmetric Diels–Alder reaction between diphenylvinylphosphine and 2-furyldiphenylarsine successfully generates a single product isomer containing the oxanorbornene skeleton which consequently gives an optically active arsinophosphine upon liberation from the metal template.

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关键词

Asymmetric Diels–Alder,Chiral metal template,Optically active arsinophosphine,Vinylphosphine,Arsine substituted furan

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