Synthesis and Crystal Structure of [Ni(phen)3 ]2[V4O12] * 7H2O.
SOLID STATE PHENOMENA(2003)
摘要
New inorganic-organic hybrid compound was synthetized hydrothermally from the system KVO3-phen-NiCl2 . 6 H2O-H2O (phen=1,10-phenantroline). The molar ratio of KVO3 : phen : NiCl2 . 6 H2O was 2 : 2 : 0.5. After 3 hours at 140 degreesC were formed white crystals of [Ni(phen)(3)](2)[V4O12] . 7 H2O as negligible phase of the mixture. This compound contains cyclic tetravanadate anion [V4O12](4-), [Ni(phen)(3)](2+) complex cation and seven molecules, of crystal water. The water molecules occupy the cavities in the crystal structure.
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关键词
cyclic tetravanadate anion,1,10-phenantroline,structure analysis,nickel(II) complex
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