A biomimetic-like radical approach to furanoditerpenes
TETRAHEDRON LETTERS(1995)
摘要
A highly stereoselective oxidative free-radical cyclization of polyene 9 has been demonstrated as a one step entry to a complex tricarbocyclic synthon 10 which contains five crucial stereogenic centers. An entry to the spongian and marginatane furanoditerpenes has been realized from synthon 10.
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关键词
free radical
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