Kinetic study on reactive extraction for chiral separation of phenylsuccinic acid enantiomers

Scientia Sinica(Chimica), pp. 137-143, 2011.

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Keywords:
reactive extractionLewis cellkineticsphenylsuccinic acid enantiomerschiral separation

Abstract:

The kinetics of the extraction of phenylsuccinic acid (PSA) enantiomers by hydroxypropyl-β-cyclodextrin (HP-β-CD) in a modified Lewis cell was studied, in which HP-β-CD dissolved in 0.1 mol L−1 NaH2PO4/H3PO4 buffer solution (pH = 2.5) was selected as the chiral extractant. PSA enantiomers were extracted from organic phase to aqueous pha...More

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ZH反应萃取手性分离苯基琥珀酸对映体动力学研究
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