Synthesis, structural, magnetic and high frequency EPR studies on a hexametallic Fe(III) complex with a highly rhombic S=5 ground state
Inorganica Chimica Acta(2008)
摘要
[Fe6O2(OH)2{C4N2H2SMe}2C(OH)O}2(tBuCO2)10] consists of two co-planar [Fe3(μ3-O)]7+ triangles, a structural type which gives rise to a well isolated S=5 spin ground state. HF-EPR reveals a substantial negative zero-field splitting but also a high rhombicity (E/|D|=0.27), explaining the absence of SMM behaviour in this class of complex.
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关键词
Iron clusters,High spin ground states,Magnetic studies,HF-EPR
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