B-Spline-Based Complex-Rotation Method with Spin-Dependent Interaction

We present a B-spline-based complex-rotation (BSCR) method with spin-dependent interaction for the study of atomic photoionization leading to multiple ionization channels dominated by doubly excited resonances for two-electron and divalent atoms. The degree of mixing between different spin states and between the bound and continuum components of the state function of the resonance state can be easily identified in the BSCR method. Its application to Mg photoionization gives good agreement with observed singlet-triplet mixed Mg spectra.