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A Theory Of Void Formation In Charge-Stabilized Colloidal Suspensions At Low Ionic Strength

JOURNAL OF CHEMICAL PHYSICS, no. 10 (2000): 4683-4698

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Using a carefully justified development of Debye-Huckel theory for highly asymmetric electrolytes, one finds that a region of expanded phase instability, or miscibility gap, can appear for charge-stabilized colloidal suspensions at high charges and low ionic strengths. It is argued that this offers a straightforward explanation for the ob...更多

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