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Chain microstructure of homogeneous ethylene-1-alkene copolymers and characteristics of single site catalysts using a direct 13C NMR peak method. Part II. Application to ethylene-propylene copolymers showing inversion

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, no. 4 (2006): 738.0-746.0

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Abstract

All relevant C-13 NMR signals of a series of 19 homogeneous ethylene-propylene copolymers were used to fit the first-order Markov reactivity ratios of the catalyst and the theoretical feeds. The copolymers cover a broad range of comonomer incorporations, from 17.0 to 56.5%, and show both primary (1,2) and secondary (2,1) insertions. As ex...More

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