A Very Useful And Efficient Wacker Oxidation Of Higher Alpha-Olefins In The Presence Of Per(2,6-Di-O-Methyl)-Beta-Cyclodextrin

Eric Monflier,Sébastien Tilloy,Georges Fremy,Yolande Barbaux,André Mortreux

TETRAHEDRON LETTERS（1995）

引用 37|浏览7

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摘要

Oxidation of higher alpha-olefins (C-8-C-16) in a two phase system with a multicomponent catalytic system, ie. PdSO4 / H9PV6Mo6O40 / CuSO4 and per(2,6-di-o-methyl)-beta-cyclodextrin gives the corresponding 2-ketones in high yields (> 90 %).

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关键词

WACKER OXIDATION, HIGHER ALPHA-OLEFIN, PER(2,6-DI-O-METHYL)-BETA-CYCLODEXTRIN

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