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Intramolecular addition reactions of carbonyl ylides formed during photocyclization of aryl vinyl ethers

JOURNAL OF ORGANIC CHEMISTRY, no. 19 (1992): 5572-5578

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Abstract

Photocyclization of aryl vinyl ethers reportedly proceeds via carbonyl ylide intermediates. The photochemical behavior of several aryl vinyl ethers, which incorporate a pendant alkene side chain, was explored. Naphthyl vinyl ethers 1c and 1d provided products that are consistent with photocyclization and subsequent intramolecular ylide-al...More

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