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Catalytic hydroxylation of phenol by hydrogen peroxide. Kinetic study and comparison between solid acids and titanosilicates

Studies in Surface Science and Catalysis, (1993): 455-462

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Abstract

Hydroxylation of phenol by hydrogen peroxide over solid acids exhibits an autocatalysis that has never been described in earlier works. The induction period is dependent on the acidity and is reduced by initial addition of dihydroxybenzenes or other electron-transfer agents. A new mechanism, initiated by the slow formation of dihydroxyben...More

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