Soluble poly(p-phenylenevinylene)s through ring-opening metathesis polymerization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2007）

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摘要

Ring opening of substituted cyclophanedienes by ruthenium-based metathesis catalysts gives sol. phenylenevinylene homopolymers of well-defined mol. wt. with an alternating cis-trans microstructure. The living character of this polymn. is demonstrated by controlled chain extension. [on SciFinder (R)]

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关键词

cyclophanes,metathesis,poly (p-phenylenevinylene)s,ring-opening polymerization,soluble polymers

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