Estudos termoanalíticos de sais de sódio e potássio de ditiocarbamatos em atmosfera oxidante

QUIMICA NOVA(2008)

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摘要
Thermoanalytical behavior of sodium and potassium salts of pyrrolidinedithiocarbamate (pyr), piperidineditiocarbamate (pip), morpholinedithiocarbamate (mor), hexametileneiminedithiocarbamate (hex), were investigated. In a first step the salts were synthesized and characterized by infrared spectroscopy (FTIR), H-1 and C-13 nuclear magnetic resonance (NMR) and elementar analysis. Finally, thermal analytical (TG/DTG and DSC) studies were performed in order to evaluate the thermal stability, as well as the pathways of the thermal decomposition based in the intermediate and final decomposition products.
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关键词
dithiocarbamic acid,thermal behavior,themal analytical
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