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A Recurrent Novel Motif for 3-Dimensional Magnetic Exchange Interactions in Chain Structures Containing Endo-Bidentate Α-Di-imine Ligands: Π-Π Overlap Interactions

Molecular crystals and liquid crystals science technology Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology Section A, Molecular crystals and liquid crystals(1995)

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摘要
Weakly associated five coordinate monomers based on high-spin trivalent iron alpha-di-imine complexes are found to exhibit surprisingly strong magnetic exchange interactions that lead to easily discerned 1-and 3-dimensional antiferromagnetic exchange and ordering effects respectively.
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