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Large anhydrous polyalanine ions: substitution of Na+ for H+ destabilizes folded states

International Journal of Mass Spectrometry, no. 1 (2001): 87-100

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Abstract

The conformations of a series of anhydrous sodiated polyalanine ions ([Alan + 3Na]3+, where n = 18–36) have been examined in the gas phase by ion mobility measurements and molecular modeling simulations. The experimental results indicate that these ions exist as highly extended conformations. There is no strong evidence for a folded state...More

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