Molecular Origin of the Temperature-Dependent Energy Migration in a Rigid-Rod Ladder-Phenylene Molecular Host
ADVANCED MATERIALS(2006)
摘要
Excitation diffusion is studied in a molecular host doped with a luminescent guest. An atomistic model based on the coupling of the electronic excitations to low-frequency intramolecular vibrations reproduces remarkably well the measured temperature-dependent host-to-guest energy transfer efficiency (see Figure).
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