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Spontaneous Imbibition Dynamics Of An N-Alkane In Nanopores: Evidence Of Meniscus Freezing And Monolayer Sticking

PHYSICAL REVIEW LETTERS, no. 17 (2009): 174501-174501

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pubmed.ncbi.nlm.nih.gov academic.microsoft.com arxiv.org

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kinetics

Abstract

Capillary filling dynamics of liquid n-tetracosane (n-C24H50) in a network of cylindrical pores with 7 and 10 nm mean diameter in monolithic silica glass (Vycor) exhibit an abrupt temperature-slope change at T-s 54 degrees C, similar to 4 degrees C above bulk and similar to 16 degrees C, 8 degrees C, respectively, above pore freezing. It ...More

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Simon Gruener

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Patrick Huber

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