A highly efficient regioselective addition of acetylides to enediones based on steric effects.

Xiaoqiang Han,Chuan Wan,Dongyan Yang,Xiaoyong Yuan,Shijie Du,Yumei Xiao,Zhaohai Qin

MOLECULES（2013）

引用 6|浏览23

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摘要

A simple and efficient strategy for the synthesis of 1-ethynylcyclohex-2-enol derivatives was developed utilizing regioselective addition of acetylides to enediones based on steric effects. Further investigation of the substrate scope of enediones indicated that all the addition reactions ocurred in good yield.

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关键词

regioselective addition,acetylides,enediones,steric effects,1-ethynylcyclohex-2-enol derivatives

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