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Relationship of Spectral Characteristics and Crystal Morphology of H-Wo3 Nanoplates

Micro/Nanotechnologies and Electron Devices(2012)

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摘要
Nanocrystals of h-WO3 (P6/mmm, PDF 33-1387) with uncommon morphology of nanoplates with ~10 nm thickness and up to 200 nm in diameter have been precipitated with nitric acid from aqua ammonium tungstate solution. The h - β phase transition occurs at T= 385°C as it have been established with DTA and XRD measurements. IR and Raman spectra have been recorded for precipitated and calcined phases. These crystals show some specific features explained as an effect of uncommon micromorphology and nanosize range geometry.
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关键词
Raman spectra,X-ray diffraction,calcination,crystal morphology,differential scanning calorimetry,infrared spectra,nanofabrication,nanostructured materials,precipitation (physical chemistry),solid-state phase transformations,tungsten compounds,DTA,IR spectra,Raman spectra,WO3,XRD,aqua ammonium tungstate solution,calcination,crystal morphology,nanocrystals,nanoplates,phase transition,precipitation,size 10 nm,spectral property,temperature 385 degC,Nanoplate,h-WO3,micromorphology
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