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Polymer Crystallization In 25-Nm Spheres

PHYSICAL REVIEW LETTERS, no. 18 (2000): 4120-4123

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Crystallization within the discrete spheres of a block copolymer mesophase was studied by time-resolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization by strong interblock segregation even though the amorphous matrix block is well above its glass trans...更多

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