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Soap Froths And Crystal Structures

PHYSICAL REVIEW LETTERS, no. 16 (2000): 3528-3531

Cited: 130|Views29
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Abstract

We propose a physical mechanism to explain the crystal symmetries found in macromolecular and supramolecular micellar materials. We argue that the packing entropy of the hard micellar cores is frustrated by the entropic interaction of their brushlike coronas. The latter interaction is treated as a surface effect between neighboring Vorono...More

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