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Reversible and irreversible interactions of poly(3-hexylthiophene) with oxygen studied by spin-sensitive methods.

JOURNAL OF PHYSICAL CHEMISTRY B, no. 46 (2011): 13513-13518

Cited: 71|Views26
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Abstract

Understanding of degradation mechanisms in polymer:fullerene bulk-heterojunctions on the microscopic level aimed at improving their intrinsic stability is crucial for the breakthrough of organic photovoltaics. These materials are vulnerable to exposure to light and/or oxygen, hence they involve electronic excitations. To unambiguously pro...More

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