A Mild Benzannulation Through Directed Cycloaddition Reactions.
Angewandte Chemie(2012)
Abstract
Simple as ABC: Alkynyl borane cycloadditions can be substrate-directed to assemble aromatic difluoroboranes within an extremely mild and efficient reaction manifold compared to that of traditional methods (see scheme). The aromatic boranes are readily transformed into a range of useful products.
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Key words
boron,cross-coupling,cycloaddition,heterocycles,synthetic methods
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