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Evidence of natural isotopic distribution from single-molecule SERS.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, no. 7 (2009): 2713-2716
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摘要
We report on the observation of the natural isotopic spread of carbon from single-molecule surface-enhanced Raman spectroscopy (SM-SERS). By choosing a dye molecule with a very localized Raman-active vibration in a cyano bond (C N triple bond), we observe (in a SERS colloidal liquid) a small fraction of SM-SERS events where the frequency ...更多
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