Synthesis Of Chiral Alpha-Amino Tertiary Boronic Esters By Enantioselective Hydroboration Of Alpha-Arylenamides

Naifu Hu,Guoqing Zhao,Yuanyuan Zhang,Xiangqian Liu,Guangyu Li,Wenjun Tang

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY（2015）

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摘要

The rhodium-catalyzed asymmetric hydroboration of alpha-arylonamides with BI-DIME as the chiral ligand and (Bpir)(2) as the reagent yields for the first time a. series of alpha-amino tertiary boronic esters in good yields and excellent enantiosolectivities (up to 99% ee).

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