A Unique Alkylation of Azobenzenes with Allyl Acetates by RhIII-Catalyzed C–H Functionalization

Organic Letters(2015)

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摘要
A novel RhIII-catalyzed direct alkylation of azobenzenes with allyl acetates through C–H activation and functionalization is demonstrated in which the allyl acetates serve as unique alkylation agents. The rhodium-catalyzed alkylation provides a highly efficient and atom-economic approach to a series of azo compounds.
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