Total Synthesis Of Gelsenicine Via A Catalyzed Cycloisomerization Strategy

Eric T Newcomb,Phil C Knutson, Blaine A Pedersen,Eric M Ferreira

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY（2016）

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摘要

The first total synthesis of (+/-)-gelsenicine is reported. The synthetic route is highly efficient (13 steps), featuring (1) a pivotal metal-catalyzed isomerization/rearrangement process that forges the central core of the molecule and (2) two facile C-N bond-forming steps that establish the flanking heterocycles.

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