Stereoselective synthesis of (+)-1-deoxyaltronojirimycin
Natural Product Research(2016)
摘要
A stereocontrolled, facile and high-yield approach for producing (+)-altroDNJ, has been developed starting from the inexpensive commercial cis 2-butene-1,4-diol. Sharpless epoxidation and a subsequent dihydroxylation were used for the introduction of all stereocentres; finally, the ring closure under basic conditions afforded the piperidine heterocycle.
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关键词
Iminosugar,stereoselective synthesis,heterocycles,dihydroxylation,1-deoxyaltronojirimycin
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