Synthesis and Absolute Configuration of Zonarol. A Fungitoxic Hydroquinone from the Brown Seaweed Dictyoptfris Zonarioides(1)
Bulletin des Sociétés Chimiques Belges(2010)
摘要
A total synthesis of both the enantiomers of zonarol 1 was accomplished. Measurements of the ORD‐CD spectra of two bicyclic intermediates coupled with direct comparison of the natural and synthetic zonarol 1 established the absolute configuration of the naturally occurring (+)‐zonarol 1 as 1R, 4aR, 8aR.
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关键词
fungitoxic hydroquinone,zonarol
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