Design and Syntheses of Poly(Norbornenyldecaborane) Precursors to Boron Carbide and Boron-Carbide/Silicon-Carbide Ceramics

Xiaolan Wei,Daniel T. Welna,Jared D. Bender,Larry G. Sneddon,Harry R. Allcock

MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS（2005）

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摘要

Poly(norbornenyldecaborane) (PND) was synthesized via ruthenium catalyzed ring opening metathesis polymerization and was found to be a good single-source polymeric boron carbide precursor. Polymer blends of PND and allylhydridopolycarbosilane (AHPCS) were also found to be excellent precursors to boron-carbide/silicon-carbide composite materials.

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